What you can do is remove body fat from your entire body. Basically, you have to decrease your overall body fat composition if you want to lose weight from any specific place on your body. When you do that, you are going to eventually target the part of your body you want and you're going to lose body fat there. You can't just do 1000 push-ups every day and lose arm fat. Instead, you have to lose body fat in your entire body while building those arm muscles. You build up those muscles so that when your body fat percentage is low enough, they can show through.
Exercise acts as a temporary diversion to daily stresses and it improves self-esteem. Increased core temperature during exercise may lead to reduced muscle tension and favourable alterations in brain neurotransmitters. Mood improvements may also occur due to the increased secretion of endogenous (internal) opiates, e.g. endorphins. Psychological changes may occur because of changes in norepinephrine, dopamine and serotonin, all hormones which can affect mood and anxiety levels.
Push-ups aren’t everyone’s cup of tea, but when you’re trying to get rid of that excess arm fat, they’re a pretty killer workout. Push-ups not only tone your biceps and triceps, they’re a great way to build muscle on your chest, making you feel stronger and look leaner in the process. If the thought of doing traditional plank push-ups has you feeling nervous, try doing the same motion at a 45-degree angle against a wall; you’ll get a similar workout, but without the intensity of a traditional push-up.